On the chargetransfer excitations in azobenzene maleimide. Study on the reactions of azo compounds with acyl halides. Compounds containing one or more azo groups nn linked to two carbon atoms have a variety of uses. Studies on synthesis and spectral characterization of some.
Synthesis and identification symmetrically azo dyes. Synthesis, characterization of new azo compounds and their. Azo compounds as a family of organic electrode materials. A study of the inhibition of tumor growth in mice and rats with azo compounds. Likewise, several case studies have linked azo pigments with basal cell carcinoma.
Preparation of azo compounds for the study of inhibition. Compounds 183 are convenient photochemical azo precursors. Reduction azides are reduced to tinsubstituted amines by. When the reactivity of the aryl group is increased by the presence of electron donor substituents or fused rings, the direct cn bond formation leads to. Synthesis of azo compounds organic chemistry portal. A detailed theoretical uv study of some azoacrylate.
Azo dyes are extremely important in variety of industries for variety of technical purposes. Epr spin trapping study of the decomposition of azo compounds in aqueous solutions by ultrasound. Photochemical and electronic properties of conjugated bis. A green dehydrogenation of hydrazo compounds using basic alumina or kfalumina under solventfree conditions afforded azo compounds in good to excellent yields. Molecules 2010, 15 5625 synthesis of azo compounds a3h, a3oh, a3ch3, a 3f, a3cl and a2cl diazotization of anilines a solution of pchloroaniline 10 mmol and 3m hcl 8 ml was heated. The most important contribution of azo compounds to radical chemistry is in their role as reaction initiators. The mixture was cooled to 0 c in an ice bath with stirring. Asian journal of research in chemistry and pharmaceutical.
The study indicated that the type of lateral groups and their position adversely affects the mesomorphic properties of these compounds. In the following, we have summarized some recent syntheses of azo dyes and. Pdf synthesis and spectroscopic study of naphtholic and. However, such compounds are seldom used as polymerization initiators and further discussion on this subject is beyond the scope of this chapter. Reduction azides are reduced to tinsubstituted amines by reaction with tin hydrides. A number of studies have shown that, in aqueous media, many azodyes, and. Synthesis and characterization of azo compounds and study of the. Most common method variables are column chemistry stationary phase. Variation in molecular stacking resulting from the. Aryl azo compounds are usually stable, crystalline species. Epr spin trapping study of the decomposition of azo.
The atomic groups attached to the nitrogen atoms may be of any organic. Journal of chemical and pharmaceutical research, 2016, 85. In general azo resorcinol compounds can exist in azo hydrazone tautomeric forms. Pdf new directions in the chemistry of azocompounds. Azo dyes represent vital components to the fabrics and textiles industries, and diazonium salts are the building blocks that these compounds are made from. General procedure for the synthesis of amides from azo compounds by smticl 4. Synthesis of most azo compounds involves diazotization of a primary aromatic amine. Azobenzene is the prototypical aromatic azo compound.
The unit containing the nitrogennitrogen double bond is called an azo group. The study indicated that the type of lateral groups and their position adversely. Our interest in this molecule stems from its ability to act as a diamine. New directions in the chemistry of azocompounds research. Biodegradation of azo dye compounds premier publishers. Novel compounds 222hydroxy4nitrophenyl hydrazono1,3diphenyl propane1,3dione and 222hydroxy4nitrophenyl hydrazono1phenyl butane1,3dione are prepared on the. Azo compounds are compounds bearing the functional group diazenyl r. Classifications, properties, recent synthesis and applications of azo. Study the electrical conductivity for a new azo compound. Hence, a series of naphtholic azo dyes 19 were synthesized via diazotization of substituted aniline. Aldamineheterocyclic ligands have been prepared through condensation step to formation aldamine compound as a starting compound for production all ligands in this study, which is used in. New azo mesogenic compounds with oh, ch 3, cl, and f side groups on the central benzene nucleus were synthesized. Some of the azo compounds are studied as hiv inhibitors of viral replications25. Further work on transformation of the cobaltii complex of 2.
Synthesis, azo compounds, guanine and, biological activity, bacteria introduction azo ligands of heterocyclic. Gaskelld, xiulin fana, ji chena, tao denga, ruixing. Defining threshold levels for the extracted compounds compliance. Where r and r are arene groups more stable than alkyl groups. Combinatorial synthesis of azo dyes linfield college. Developing a method for the analysis of azo dyes using the. Azo compounds are very important molecules and have attracted much attention in both academic and applied research 1520. Mostly, synthesis of azo compounds involves diazotization of substituted primary. Azo compound, any organic chemical compound in which the azo group. Biodegradation of azo dye compounds kamlesh shah department of biotechnology, p. The antibacterial activities of the compounds were studied using gram positive and gram negative microorganism. Azo compounds as a family of organic electrode materials for alkaliion batteries chao luoa, oleg borodinb, xiao jia,c, singyuk houa, karen j. A detailed theoretical uv study of some azo acrylate compounds.
The azo components used were 8hydroxyquinoline, resorcinol, pyrogallol, and 7iodo8hydroxy5quinolinesulfonic acid, while the diazol components were sulfanilamide and a number of its derivatives. Synthesis and characterization of azo compounds and study. Photoswitchable systems with chargetransfer ct transitions have gained much attention during the recent years because of their many emerging applications. Azo dyes are organic compounds bearing the functional group r. Azo dyes represent the largest production volume of dye chemistry. Applying different extraction procedures and different analytical technologies toxicological assessment.
Azo dyes are class of compounds containing a nn double bond generally connected to aromatic ring, due to their ability to absorb visible light and ease of. As well as the study was achieved through the complexes formed between these a new prepared symmetrically azo dyes. They are compound bearing the functional group rnnr in which r and r can be either alkyl or aryl groups. Study of removal techniques for azo dyes by biosorption.
Irradiation at 254 nm photochemically cleaves the ring and the resulting azo compounds often absorb little at these wavelengths and the. We have investigated the photophysical, photochemical and electrochemical properties of two bis azo derivatives, e,e. Under nitrogen atmosphere, 1 mmol of azo compound 1 dissolved in dry thf 1 ml was added to the solution. Synthesis of some azo compounds and a study of their properties. Density functional study cavus ms 1, gur m 2, vurdu cd 1, kocaokutgen h 4, sayiner g 3 and kandemirli f 1. The environmental, health and economic impacts of textile.
Molecules 2010, 15 5625 synthesis of azo compounds a3h, a3oh, a3ch3, a 3f, a3cl and a2cl diazotization of anilines a solution of pchloroaniline 10 mmol and 3m hcl 8 ml was heated gently, then water 10 ml was added in order to dissolve the solid. Azo dye release in industrial effluent can also have an impact on human health in certain countries. Synthesis of some azo compounds and a study of their. Pdf on aug 1, 2011, omer rasheed published new directions in the chemistry of azocompounds find, read and cite all the research you. Variation in molecular stacking resulting from the different polarity of liquid crystalline molecules. Biological studies of syntheised azo compounds of indole. They are a commercially important family of azo compounds, i. Antioxidant activity study hala s alatbi, bushra k alsalami and iqbal j alassadi university of basrah,college of science, department of chemistry,basrahiraq. Gromova, practical manual of spectrophotometry and. Synthesis, spectroscopic, thermodynamics and kinetics. Azo group is stabilised by becoming part of extended delocalised. The two compounds, which can be viewed as being composed. Potential for use as sonodynamic sensitizers for cell killing.
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